I wish to learn making new maps but I don't know how and what software is needed for it
Can anyone help me?

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HI!
I am a cs mapper and got your question.I know how but it will take time and nerves to me to teach you.
I will give you the page I thank my skills as a mapper.The link is:
http://www.superjer.com/learn.php
Hope it helped you

Thank you!!!!!
But there are some texture like "SKY","SKIP","NULL","HINT" in zhlt.wad , I'm not sure how to use them.

Those are special textures:
SKY - the engine will apply the sky textures where it finds the sky texture.
SKIP and HINT - are for wpoly optimization (for advanced mapping)
NULL - the engine will not draw the faces that have the 'NULL' texture applied to it.

But once I use SKY, there are only one sky view, how can I get more view

You can change the sky by changing its name in Map->Map properties... ->environment map (cl_skyname).
Here are the default skies in Counter Strike:

backalley


badlands


blue


city1


des - this is the default sky (if no name is entered in map properties)


drkg


forest


green


grnplsnt


morningdew


office


snow


snowlake_


trainyard

Do anyone know how to put models in the map , I can't find in the Tutorials

You can place *.mdl using cycler_sprite entity.

click the image for a larger view

THX
But after I add the model using your way, a Fatal error comes out and say "Mod_NumForName:C:/............mdl not found"
P.S. '..........' is a very long link
Also when I add the model, I can't see the model as you see in your picture

First of all, place your *.mdl file in cstrike/models, and load it from there.
Second, »Valve Hammer Editor 3.5 (598.1 KB) has support for models so it would be a good idea to upgrade .
You need VHE 3.4 to upgrade to version 3.5. Unzip anywhere then copy-paste hammer.exe over the one you already have (default located in C:/Program Files/Valve Hammer Editor).

THX a lot, but just one problem is fixed
After I add the model using your way, a Fatal error comes out when I run CS and say "Mod_NumForName:C:/............mdl not found"
P.S. '..........' is a very long link

I have place the *.mdl file in cstrike/models, and load it from there.
but the problem is not solved

In that case VHE is probably configured wrong.
Does your VHE Game Configuration tab look like the one in the screenshot?

click the image for a larger view

yes , but the problem is not solve

Did you put the model in ...steamapps\steam_username\counter-strike\cstrike\models?
If yes, did you load it in VHE from that location?